A fun show opportunity next month. Mountain Home is in the north-central part of Arkansas and is only 4 and a half hours away, same as a trip to St. Louis. If you like quartz, Arkansas is famous for it and I’m sure you will see lots of it. I also hear the show will have plenty of air conditioning!
MOZARKITE, MISSOURI’S STATE STONE by Roger K. Pabian
(Editor’s note: This article was written by Roger and printed in The Gemrock in 2002. It is written about a field trip taken by Roger and Bill and Betty White.)
On May 3, I took a trip to Kansas City and then on to Lincoln, Missouri, to examine the in place occurrence of Mozarkite, the Official State Gemstone of Missouri. As part of my ongoing study of cryptocrystalline and amorphous quartz family gemstones, I thought that the Mozarkite mine would be a worthwhile trip.
In Kansas City, I joined up with Bill and Betty White on Friday afternoon. Bill and I spent much of the afternoon at one of the major tool houses there and I purchased quite a few diamond tools and other tools that would be of use for stone and metal work. We also hit one of the retail salvage outlets, a store that carries distressed merchandise, as they often have many tools of considerable value for very low prices.
On Saturday morning about 7:00 A.M. we left Independence for the small town of Lincoln, Missouri. The town is famous for its annual rock swap in September. There we teamed up with Linville Harms, owner of the Mozarkite mine, and then went on to the mine. The attached photos of the Mozarkite and the Mozarkite mines help you get a better idea of what the site is like.
Mozarkite is not an accepted mineral name but is simply a trade name that was developed to promote the acceptance of the stone as Missouri’s official State Gem and to generate sales to both lapidary and tourists. The name has found acceptance in some circles but is not an acceptable mineral name in others.
Mozarkite has formed in place in marine sedimentary rocks of Ordovician age — it probably is most common in the Jefferson City Formation. The Jefferson City Formation is comprised mostly of dolomite with silty and cherty stringers running through it. There are very few fossils in dolomized rocks as the addition of magnesium to the calcium carbonate of the limestone usually results in complete re-crystallization of the rock and destruction of any fossils or sedimentary structures therein. We did observe a fragment of a brachiopod shell that escaped destruction. It appeared to be a flat-shelled, long-hinge lined form, probably a strophomenoid, but no other determination could be made of it. Much of the local lore about Mozarkite attributes it to igneous activity but there is no evidence for any in that area of Ordovician or younger rocks.
The Mozarkite appears to be of strictly marine sedimentary origin. Some of the nodules show evidence of an accumulation of siliceous gel or ooze on their outer surfaces.
There appears to be three different facies of Mozarkite. The gemmy kind is a dense, brittle form that shows no crystallinity at 10X magnification. A second kind is what the locals call “sugary” Mozarkite. Some of this is quite colorful and has interesting patterns and enjoys some gem use. The “sugary” kind, However, this does not polish nearly as well as the dense, brittle kind. Then, there are some nodules that appear to be very fine sandy textured.
The three facies or textures of Mozarkite suggest that sorting of particles may have been one of the key factors in the origin of the material. Sorting of particles simply means that as some energy form such as wind or flowing water moved a mixture of unconsolidated particles, the heaviest or largest particles are the first ones to drop out of suspension. You can observe this phenomenon on the gravel bars of a stream or in the bars along beaches, estuaries, or lagoons. The coarsest particles will be on the upstream end of the bar or nearer the bottom of the bar. It may well be that the gem Mozarkite is a quartz argillite, a sedimentary rock made up of quartz particles of clay size, that is, smaller than 1/256th of a millimeter. The gemmy facies could also be derived from silica of organic or volcanic origin. The “sugary” facies is made up of the particles larger than 1/16th but smaller than 1/4 mm.
The source for the silica that makes up Mozarkite is currently not known. It may have been from Precambrian granite rocks that are found to the south and east. Sponge spicules may have been the source of silica; I will not totally disregard them. However, I usually favored volcanic ash as the source of siliva for large bodies of chert or flint in marine sedimentary sequences. If there was any volcanic activity involved with Mozarkite, it was from volcanoes that were far away from the Mozarkite-bearing strata.
Mozarkite is a very interesting gem material that could shed a lot of light on the geologic events and processes that led to its formation. My comments above are only a few ideas about its occurrence. Like many other ideas on his stone, my hypotheses need more documentation before they can either be accepted or rejected. My hypotheses should probably read as follows: “Mozarkite is a quartz argillite of marine sedimentary origin that formed in situ in shallow seas of Ordovician age. The source of the quartz is shield rocks of Precambrian ages that lie to the southeast of the area from which it is not found.”
To prove that, several things need to be done. First, properly oriented (top and north) nodules need to be collected from in place in the mine pits. The nodules should not be examined in the field to avoid “high grading” the material. An outcrops map or diagram would need to be made that shows the places from which each nodule was taken. Similar sampling should be carried out from several different layers in several different parts of the mine. The facies of each nodule would need to be located on the map. Does one zone produce only sandy material whereas another produces only gemmy material? Or do these facies occur at random? Thin sections (30 microns) would have to be made. The nature of the particles (angular or rounded) and any cement between them would need to be noted. Is there a silica cement between the particles or does their angularity hold them together? Then other occurrences, both geographic and stratigraphic, of Mozarkite would have to be noted. The sedimentary structures in the Mozarkite and the host rock would also have to be observed and recorded.
By the time all of this is done, one has done enough work to earn a Master of Science Degree. As you see, there is no easy answer for Mozarkite. Perhaps, as a club, or group of clubs, we might think of funding a student to carry out the above kind of research.
The Association Picnic will be Sunday, August 27 at Antioch Park. 6501 Antioch Rd, Merriam, KS 66202. There will be a swap starting around 8 am, lunch will be around noon, and then the auction will be sometime after lunch. Please bring a side dish or dessert, stuff to swap if you want to swap, and cash so you can buy something at the auction. Proceeds go to the Scholarship Fund.
Show-Me Rockhounds member Dan Snow has provided these geologic maps of Kansas City from 1917 which contain topographical, geological, and cross-sectional data. The maps show where to find several different types of rocks common to this area. They are also a great way to see how Jackson County has changed in the last 100 years. The maps are in PDF format and are very high resolution, so please zoom in!
This is from the Musonoi Extension mine, near Kolwezi, Shaba Province, Zaire, from the collection of Michael Scott. The Rruff Project used single-crystal X-ray diffraction to confirm the identity of the cuprosklodowskite. It is basically Sklodowskite (named after Marie Sklodowska Curie) that contains copper.
Next weekend (June 10, 2017) we are going on a trip to the Missouri Mines Rock Swap in Park Hills, Missouri. We will look for drusy quartz and possibly Missouri banded agates. The swap itself goes from June 9-11 if you want to stay longer and is located at the Missouri Mines Historic Site near St. Joe State Park, 4000 MO-32, Park Hills, Missouri 63601. FREE admission to the show!
Directions: From Missouri 32, get off at Federal Mill Rd and look for the Missouri Mines Historic Site. Google Maps
At the end of our meeting on May 20, 2017, David said, “Hey, we should go to [redacted] to get some fossils. It’s really close by.” Several members came along and looked for fossils.
We had to climb a little bit to get to the good spot, but once we did, there were crinoid stems, brachiopods, encrusting and branching bryozoa, and other things. It was easy to get fossils out of the ground because it had recently rained. Afterward, David suggested another place nearby to go to find composita, so some people came along for that, too.
In the summer weather, we expect to go on more spontaneous field trips like this in the Kansas City area. Make sure you come to our meetings dressed for adventure* if you want to come along!
*dressed for adventure= long pants, closed toe shoes, bring gloves and bug spray
Update: We took another mini field trip in July.
Here is some fluorite (purple) and calcite (yellow) on sphalerite (silver). No further comments, I just thought this was pretty.
Stalactites and stalagmites form in caves when water that contains dissolved minerals (such as calcium carbonate) drips from the ceiling. Scientists can analyze the 18O/16O ratios (isotopes of oxygen) in the stalactites and see how the temperature changed as they were formed. A team led by Andy Baker, Gurinder Nagra, and Pauline C. Treble of the University of New South Wales, Australia discovered that Yonderup Cave had a lot more 18O than they expected. Since having more 18O is associated with higher temperatures at the time of formation, it could have been interpreded as one of the largest climate changes in the last 2 million years.
But, there was a wildfire in 2005 and a large tree died right on top of the cave. Baker’s team believes that this is what actually caused the increased 18O concentration. This is important for anybody else trying to use these oxygen isotopes to determine ancient temperatures, because if they get a very warm result it might have been caused by a forest fire instead.
It’s a little more complicated than that. Read the whole article here: http://cen.acs.org/articles/94/i30/Cave-dripwater-contain-fire-evidence.html and check Baker’s website for more interesting stuff about how he researches caves to learn about past climates.
A while ago, we went over to Mr. and Mrs. Snow’s house and learned how to make cabs. Dan provided the equipment and Connie provided a delicious lunch and took photos so I would have something to write about. Everyone had a lot of fun.